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Department of Materials Science and Engineering


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robinson

Richard Robinson

Richard D Robinson

Department Faculty

Office: 127 Bard
Phone: 607.255.7750
Email: rdr82@cornell.edu

Website: Robinson Group Website

Professor Robinson’s research focuses on nanostructured materials for alternative energy applications. Our goal is to utilize the advanced properties of nanomaterials to build efficient thermoelectrics and fuel cells. By altering the size, shape, and composition of our particles we are able to tune properties important to these applications such as their band gap and thermal conductivity. Additionally our conducting metal oxide nanomaterials can be used in a variety of other energy applications where charge transport is important.

Current Research

Much of our synthetic work revolves around colloidal synthesis of nanoparticles, relying on solvothermal, air-free techniques. We use a variety of organometallic precursors and surfactant groups to control nanoparticle composition and growth rate, with the ultimate goal of structuring efficient materials specifically for thermoelectric and fuel cell applications. The particles are assembled into macro-sized materials through a variety of means en route to producing devices. To enhance our understanding of thermoelectrics we are studying the heat transport, carrier confinement, phonon boundary scattering, and thermoelectric properties in low-dimensional materials. We’re developing a monochromatic phonon source and a phonon spectrometer to accomplish this. Other fundamental research areas include the study of nanoparticle growth and nucleation, ion intercalation, and surface ligand chemistry.

Research Projects

  • Colloidal synthesis of nanoparticle metal oxides
  • Doping of nanoparticles to control electronic and thermal properties
  • Synthesis of new organometallic precursors for nanoparticles
  • In situ studies of particle nucleation and growth 
  • Nanofabrication of monochromatic phonon source at the CNF

Select Publications

  • D.O. Demchenko, R.D. Robinson, B. Sadtler, C.K. Erdonmez, A.P. Alivisatos, L.-W. Wang, "Formation mechanism and properties of CdS/Ag2S nanorod superlattices," ACS Nano 2(4), 627 (2008)
  • R.D. Robinson, B. Sadtler, D.O. Demchenko, C.K. Erdonmez, L.-W. Wang, A.P. Alivisatos, "Spontaneous Superlattice Formation in Nanorods through Partial Cation Exchange," Science 317, 355 (2007). 
  • L. M. Huang, Z.Y. Chen, J.D. Wilson, S. Banerjee, R.D. Robinson, I.P. Herman, R. Laibowitz, S. O’Brien, " Barium titanate nanocrystals and nanocrystal thin films: Synthesis, ferroelectricity, and dielectric properties," Journal of Applied Physics 100(3), 034316 (2006).
  • S. Banerjee, D.I. Kim, R.D. Robinson, I.P. Herman, Y.B. Mao, S.S. Wong, " Observation of Fano asymmetry in Raman spectra of SrTiO3 and CaxSr1-xTiO3 perovskite nanocubes," Applied Physics Letters 89(22), 223130 (2006).
  • S. Banerjee, S.G. Jia, D.I. Kim, R.D. Robinson, J.W. Kysar, J. Bevk, I.P. Herman, "Raman microprobe analysis of elastic strain and fracture in electrophoretically deposited CdSe nanocrystal films," Nano Letters 6(2), 175 (2006).
  • R.D. Robinson, J. Tang, M.L. Steigerwald, L.E. Brus, and I.P. Herman, "Raman scattering in HfxZr1-xO2 nanoparticles," Physical Review B 71(11), 115408 (2005).
  • J. Tang, J. Fabbri, R.D. Robinson, Y. Zhu, I. P. Herman, M. L. Steigerwald, and L. E. Brus, "Solid-solution nanoparticles: use of a nonhydrolytic sol-gel synthesis to prepare HfO2 and HfxZr1-xO2 nanocrystals," Chemistry of Materials 16(7), 1336-1342 (2004).
  • R.D. Robinson, J.E. Spanier, F. Zheng, S.W. Chan, and I.P. Herman, "Visible thermal emission from sub-band-gap laser excited cerium dioxide particles," Journal of Applied Physics 92(4), 1936-1941 (2002).
  • J.E. Spanier, R.D. Robinson, F. Zheng, S.W. Chan, I.P. Herman, "Size-dependent properties of CeO2-y nanoparticles as studied by Raman scattering," Physical Review B 64(24), 245407 (2001).

Awards and Recognition

Education
  • Tufts University, Mechanical Engineering, B.S.
  • Tufts University, Mechanical Engineering, M.S.
  • Columbia University, Applied Physics, Ph.D. 10/04
  • LBNL/UC Berkeley, Chemistry/Materials Science, 10/04 – 7/08
Appointments
  • Assistant Professor, Cornell University (Materials Science Dept., 2008 – present)
  • Lawrence Chemist Postdoctoral Fellow, LBNL/UC Berkeley (2004 - 2008)
  • Research Assistant – Physical Research Lab., Bell Laboratories (1999)
  • Senior Consultant, Andersen Consulting
  • Research Assistant - Thermal Analysis of Materials Processing Lab, Tufts University
Honors
  • NIST/NRC Post-doctoral Research Associateship Program (declined) 2008
  • Ford Foundation Post-doctoral Fellowship (declined) 2008
  • LBNL Award for Excellence in Technology Transfer, 2007
  • Lawrence Chemist Postdoctoral Fellow 2004 - 2008
  • Ford Foundation Pre-doctoral Fellowship, 2000 - 2003
  • NDSEG Pre-doctoral Fellowship Honorable Mention, 1999
  • Irene Diamond Pre-doctoral Fellowship, 1998
  • Tau Beta Pi Engineering Honor Society
  • Mechanical Engineering Dept. Award for Outstanding Graduate Research
  • "Who’s Who" graduate student, NSBE Region One
  • National Science Foundation Creativity Award
  • Alex Elias Memorial Prize Scholarship, Tufts University

Graduate Students

Mahmut Aksit